Influence of inhibitor addition on the corrosion protection performance of sol–gel coatings on AA2024

Sol–gel films are actively investigated during the last decade as possible candidates for environmentally friendly pre-treatments. However, the important drawback in this case is the lack of active corrosion protection and self-healing ability.     

Immobilization and activation of vanadium(III) and titanium(III) single‐site catalysts for ethylene polymerization using MgCl2‐based supports

Significant increases in the activity of vanadium(III) amidinate catalysts for ethylene polymerization have been obtained by immobilization on a MgCl₂‐based support prepared by reaction of AlEt₃ with a MgCl₂/ethanol adduct. Catalyst immobilization and activation on this type of support prevents the rapid decay in activity observed under homogeneous polymerization conditions with unsupported catalysts. Stable polymerization activity is also observed with analogous titanium(III) complexes. Polyethylene with narrow molecular weight distribution and spherical particle morphology is obtained without reactor fouling. Copyright © 2005 Society of Chemical Industry     

EIS evaluation of the filiform corrosion of aluminium coated by a cataphoretic paint

Filiform corrosion is mainly considered as a cosmetic attack and is undesirable in most applications. The initiation and propagation of the filaments are related to different parameters such as the presence of defects, the permeability of the coating to water and oxygen, the adherence of the paint system and the presence of salts.

The aim of this work is to study the behaviour of painted aluminium samples towards filiform corrosion or delamination. The 6082 Aluminium alloy was selected and the samples were covered with a cataphoretic epoxy primer without lead (PPG Industries France). Prior to the application of the electrocoat, the samples were pre-treated by a commercial Zr/Ti or chromate conversion treatment or simply etched with a commercial acid etching product.

Filiform corrosion was studied by the normalized test (ISO/DIS 4623): painted and scratched samples were inoculated in HCl and exposed in a constant humidity chamber at 40 °C and 82% RH for 3 weeks. After exposure the samples were subjected to a visual and optical microscopic examination.

Electrochemical impedance spectroscopy was used to study the sensitivity to filiform corrosion. The operating mode of this test is similar to the normalized one. The samples were scratched before inoculation for 1 h in HCl and then exposed to the humidity chamber for a maximum of 4 days. The samples were tested by EIS in an acidified 0.1 M Na₂SO₄ electrolyte solution. The resulting impedance spectra were analyzed with an appropriate equivalent electrical circuit which allows the evaluation of the exposed metallic surface area, directly related to the extent of filiform corrosion or delamination. Different parameters were varied: the exposure time in the humidity chamber; the immersion time in the electrolyte sulphate solution as well as its pH and the coating thickness.     

FeBP非晶态合金超细微粒的合成及其对PH3分解的催化作用

用化学还原法合成了FeBP非晶态合金超细微粒，用电感耦合等离子体光谱（ICP）、X射线粉末衍射（XRD）、透射电子显微镜（TEM）和差热分析（DSC）等手段对其进行了物性表征，并用微型催化反应装置考察了其对PH3分解的催化作用，结果表明，非晶态合金FeBP对PH3的分解具有良好的催化作用，能使PH3的分解温度从800℃以上降到500℃左右。490℃时分解率超过90％，540℃时达100％。     

TSM系统中高层软件测试的方法

任何一个软件，在开发过程中都不可避免地存在错误。软件测试的目的就是跟踪出软件的错误，不同种类的软件开发和测试工具是不相同的。介绍软件测试的基本概念、原理以及方法。主要介绍Telelogical Tau AB公司的TTCN的测试机理，并利用TTCN进行TSM(TD-SCDMA移动通信系统)高层信令测试的方法。     

Influence of nano-scaled dispersed second phase on substructure of deformed dispersion strengthened copper alloy

The deformation behavior of dispersion strengthened copper alloy Cu-Al2O3 was studied by TEM. The results show that nano-scaled dispersed second phase not only increases dislocation density in matrix, but also has an important influence on the dislocation substructure. The presence of fine dispersed Al2 O3 particles results in a uniform and random dislocation distribution in matrix copper and causes the difficulty in formation of dislocation cell structure and the decrease in the amount of cell structure during deformation. Deformation gives rise to much more dislocations and dislocation cells form more difficultly and the decrease in the cell size with the increase of dispersion degree.     

Preparation of Plate Fe_(60)Co_8Zr_(10)Mo_5W_2B_(15) Bulk Amorphous Alloy and Its Fracture Toughness

1Introduction Duwez[1]synthesizedthefoilAu Siamorphousalloyforthefirsttimewithrapidsolidification,whichinitiatedthepreparationofamorphousalloysintheprocessofalloysolidification,andthereaftertheresearchonamorphousal loysdevelopedrapidly.Since1980s,withthec…     

A time series bootstrap procedure for interpolation intervals

A sieve bootstrap procedure for constructing interpolation intervals for a general class of linear processes is proposed. This sieve bootstrap provides consistent estimators of the conditional distribution of the missing values, given the observed data. A Monte Carlo experiment is used to show the finite sample properties of the sieve bootstrap and finally, the performance of the proposed method is illustrated with a real data example.     

Effects of thermal and mechanical treatments on a titanium-based conversion coating for aluminium alloys

The influence of mechanical deformation and heating on the protective performance of a chromium-free conversion treatment for aluminium alloys has been assessed by polarisation and AC impedance measurements. Protection is unlikely to be seriously compromised by typical production operations.     

高镁边缘磷矿制取阻燃剂氢氧化镁的工艺

为解决大量的高镁低磷边缘磷矿废渣堆存对环境的影响,开发了以其为原料制取阻燃剂氢氧化镁工艺.该工艺主要包括酸解磷矿和镁沉淀过程,重点讨论了沉淀氢氧化镁过程中时间、温度、氨镁摩尔比n(NH3/MgO)等多种因素的影响,得到的最佳工艺条件是:反应温度65℃,反应时间80min,n(NH3/MgO)为5∶ 1,镁的沉淀效率为80%.